Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides

Sik Kim Hoon; Jun Kim Jai; Nam Kwon Hyeck; Jo Chung Moon; Gwon Lee Byung; Gyeom Jangy Ho

doi:10.1006/jcat.2001.3444

Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides

Sik Kim Hoon, Jun Kim Jai, Nam Kwon Hyeck, Jo Chung Moon, Gwon Lee Byung, Gyeom Jangy Ho

College of Science

Research output: Contribution to journal › Article › peer-review

87 Citations (Scopus)

Abstract

The poly(4-vinylpyridine)-supported zinc halide catalysts, prepared from a reaction of ZnX₂ and poly(4-vinylpyridine), exhibit high selectivity and activity for the coupling reaction of CO₂ and ethylene oxide or propylene oxide. Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr₂ catalyst and its reaction product with propylene oxide and/or CO₂ show that a pyridiniumalkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L₂ZnBr₂ (L = pyridine or methyl-substituted pyridine).

Original language	English
Pages (from-to)	226-229
Number of pages	4
Journal	Journal of Catalysis
Volume	205
Issue number	1
DOIs	https://doi.org/10.1006/jcat.2001.3444
Publication status	Published - 2002

Keywords

Carbon dioxide
Cyclic carbonate
Epoxide
Heterogeneous catalyst
Zinc complex

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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10.1006/jcat.2001.3444

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title = "Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides",

abstract = "The poly(4-vinylpyridine)-supported zinc halide catalysts, prepared from a reaction of ZnX2 and poly(4-vinylpyridine), exhibit high selectivity and activity for the coupling reaction of CO2 and ethylene oxide or propylene oxide. Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2 catalyst and its reaction product with propylene oxide and/or CO2 show that a pyridiniumalkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L2ZnBr2 (L = pyridine or methyl-substituted pyridine).",

keywords = "Carbon dioxide, Cyclic carbonate, Epoxide, Heterogeneous catalyst, Zinc complex",

author = "Hoon, {Sik Kim} and Jai, {Jun Kim} and Hyeck, {Nam Kwon} and Moon, {Jo Chung} and Byung, {Gwon Lee} and Ho, {Gyeom Jangy}",

note = "Funding Information: This work was supported by the Ministry of Science and Technology in Korea. We thank Dr. Duk-Young Han, Korea Basic Science Institute— Seoul Branch for solid-state NMR analysis.",

year = "2002",

doi = "10.1006/jcat.2001.3444",

language = "English",

volume = "205",

pages = "226--229",

journal = "Journal of Catalysis",

issn = "0021-9517",

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number = "1",

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TY - JOUR

T1 - Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides

AU - Hoon, Sik Kim

AU - Jai, Jun Kim

AU - Hyeck, Nam Kwon

AU - Moon, Jo Chung

AU - Byung, Gwon Lee

AU - Ho, Gyeom Jangy

N1 - Funding Information: This work was supported by the Ministry of Science and Technology in Korea. We thank Dr. Duk-Young Han, Korea Basic Science Institute— Seoul Branch for solid-state NMR analysis.

PY - 2002

Y1 - 2002

N2 - The poly(4-vinylpyridine)-supported zinc halide catalysts, prepared from a reaction of ZnX2 and poly(4-vinylpyridine), exhibit high selectivity and activity for the coupling reaction of CO2 and ethylene oxide or propylene oxide. Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2 catalyst and its reaction product with propylene oxide and/or CO2 show that a pyridiniumalkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L2ZnBr2 (L = pyridine or methyl-substituted pyridine).

AB - The poly(4-vinylpyridine)-supported zinc halide catalysts, prepared from a reaction of ZnX2 and poly(4-vinylpyridine), exhibit high selectivity and activity for the coupling reaction of CO2 and ethylene oxide or propylene oxide. Solid NMR characterization of the poly(4-vinylpyridine)-supported ZnBr2 catalyst and its reaction product with propylene oxide and/or CO2 show that a pyridiniumalkoxy ion-bridged zinc bromide complex is functioning as an active species, such as in the homogeneous catalysis with L2ZnBr2 (L = pyridine or methyl-substituted pyridine).

KW - Carbon dioxide

KW - Cyclic carbonate

KW - Epoxide

KW - Heterogeneous catalyst

KW - Zinc complex

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U2 - 10.1006/jcat.2001.3444

DO - 10.1006/jcat.2001.3444

M3 - Article

AN - SCOPUS:0036159906

VL - 205

SP - 226

EP - 229

JO - Journal of Catalysis

JF - Journal of Catalysis

SN - 0021-9517

IS - 1

ER -

Well-defined highly active heterogeneous catalyst system for the coupling reactions of carbon dioxide and epoxides

Abstract

Keywords

ASJC Scopus subject areas

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