Abstract
We report a new ternary Zn2SnO4 (ZSO) electron-transporting electrode of a CH3NH3PbI3 perovskite solar cell as an alternative to the conventional TiO2 electrode. The ZSO-based perovskite solar cells have been prepared following a conventional procedure known as a sequential (or two-step) process with ZSO compact/mesoscopic layers instead of the conventional TiO2 counterparts, and their solar cell properties have been investigated as a function of the thickness of either the ZSO compact layer or the ZSO mesoscopic layer. The presence of the ZSO compact layer has a negligible influence on the transmittance of the incident light regardless of its thickness, whereas the thickest compact layer blocks the back-electron transfer most efficiently. The open-circuit voltage and fill factor increase with the increasing thickness of the mesoscopic ZSO layer, whereas the short-circuit current density decreases with the increasing thickness except for the thinnest one (∼100 nm). As a result, the device with a 300 nm-thick mesoscopic ZSO layer shows the highest conversion efficiency of 7%. In addition, time-resolved and frequency-resolved measurements reveal that the ZSO-based perovskite solar cell exhibits faster electron transport (∼10 times) and superior charge-collection capability compared to the TiO2-based counterpart with similar thickness and conversion efficiency.
Original language | English |
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Pages (from-to) | 22991-22994 |
Number of pages | 4 |
Journal | Journal of Physical Chemistry C |
Volume | 118 |
Issue number | 40 |
DOIs | |
Publication status | Published - 2014 Oct 9 |
Externally published | Yes |
ASJC Scopus subject areas
- Electronic, Optical and Magnetic Materials
- Energy(all)
- Physical and Theoretical Chemistry
- Surfaces, Coatings and Films